Wave Nature of Matter 🌊
Light shows both wave and particle behaviors—interference and diffraction need waves, while photoelectric and Compton effects need photons. This mix naturally leads to the question: do particles (electrons, protons, etc.) also act like waves? The answer—yes!—opens the door to matter waves. :contentReference[oaicite:0]{index=0}
1 de Broglie’s Bold Hypothesis 💡
In 1924 Louis de Broglie suggested that every moving particle carries a wave whose wavelength depends on its momentum. He wrote:
$$\lambda \;=\;\frac{h}{p}\;=\;\frac{h}{m\,v}\qquad(11.5)$$
Here \(h\) is Planck’s constant, \(p\) the particle’s momentum, \(m\) its mass, and \(v\) its speed. This is the de Broglie relation. The left-hand side (\(\lambda\)) belongs to waves, while the right-hand side (\(p\)) belongs to particles—showing duality in one elegant stroke. :contentReference[oaicite:1]{index=1}
2 Special Case: Photons 🔆
For a photon, the momentum is \(p = \dfrac{h\nu}{c}\) (11.6). Substituting in (11.5) gives
$$\lambda \;=\;\frac{h\,c}{p}\;=\;\frac{c}{\nu}\qquad(11.7)$$
So the de Broglie wavelength of a photon is exactly the ordinary wavelength of the light itself—nice symmetry! :contentReference[oaicite:2]{index=2}
3 What Changes \(\lambda\)? 🧐
- Heavier particles (\(m\) large) ⟹ smaller \(\lambda\)
- Faster particles (\(v\) large) ⟹ smaller \(\lambda\)
Example: A 0.12 kg ball moving at 20 m s-1 has \(p = 2.40\;\text{kg m s}^{-1}\) and \(\lambda = 2.76\times10^{-34}\,\text{m}\)—far too tiny to detect. :contentReference[oaicite:3]{index=3} That’s why your cricket ball never shows diffraction!
4 Quick Calculations 🔢
Electron vs Football:
- Electron with \(v = 5.4\times10^{6}\,\text{m s}^{-1}\)
⟹ \(p = 4.92\times10^{-24}\,\text{kg m s}^{-1}\), \(\lambda = 0.135\,\text{nm}\) (similar to X-ray spacing). :contentReference[oaicite:4]{index=4} - 150 g ball at 30 m s-1
⟹ \(p = 4.50\,\text{kg m s}^{-1}\), \(\lambda = 1.47\times10^{-34}\,\text{m}\) (utterly negligible). :contentReference[oaicite:5]{index=5}
5 When Do Matter Waves Matter? 🔍
In everyday life, momenta are huge and de Broglie wavelengths are minuscule, so wave effects hide. In the atomic world—where \(m\) is tiny—\(\lambda\) reaches nanometers, matching inter-atomic distances and making diffraction experiments (like electron diffraction) possible. :contentReference[oaicite:6]{index=6}
High-Yield Ideas for NEET 🔥
- de Broglie relation: $$\lambda = \dfrac{h}{p} = \dfrac{h}{m v}$$
- For photons, \(\lambda\) from de Broglie equals the light’s own wavelength.
- \(\lambda\) decreases with increasing mass or speed—so wave behavior is prominent only for microscopic particles.
- Typical electron \(\lambda\) (≈ 0.1 nm) matches crystal lattice spacing—basis of electron diffraction.
- de Broglie’s idea links matter and radiation, paving the way for quantum mechanics.
😊 Happy studying—matter waves are real waves in the quantum playground!